Ultrasound assisted dispersal of a copper nanopowder for electroless copper activation

J. Graves, M. Sugden, R.E. Litchfield, D.A. Hutt, T.J. Mason, A. Cobley

Research output: Contribution to journalArticle

13 Citations (Scopus)
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Abstract

This paper describes the ultrasound assisted dispersal of a low wt./vol.% copper nanopowder mixture and determines the optimum conditions for de-agglomeration. A commercially available powder was added to propan-2-ol and dispersed using a magnetic stirrer, a high frequency 850 kHz ultrasonic cell, a standard 40 kHz bath and a 20 kHz ultrasonic probe. The particle size of the powder was characterized using dynamic light scattering (DLS). Z-Average diameters (mean cluster size based on the intensity of scattered light) and intensity, volume and number size distributions were monitored as a function of time and energy input. Low frequency ultrasound was found to be more effective than high frequency ultrasound at de-agglomerating the powder and dispersion with a 20 kHz ultrasonic probe was found to be very effective at breaking apart large agglomerates containing weakly bound clusters of nanoparticles. In general, the breakage of nanoclusters was found to be a factor of ultrasonic intensity, the higher the intensity the greater the de-agglomeration and typically micron sized clusters were reduced to sub 100 nm particles in less than 30 min using optimum conditions. However, there came a point at which the forces generated by ultrasonic cavitation were either insufficient to overcome the cohesive bonds between smaller aggregates or at very high intensities decoupling between the tip and solution occurred. Absorption spectroscopy indicated a copper core structure with a thin oxide shell and the catalytic performance of this dispersion was demonstrated by drop coating onto substrates and subsequent electroless copper metallization. This relatively inexpensive catalytic suspension has the potential to replace precious metal based colloids used in electronics manufacturing.

Original languageEnglish
Pages (from-to)428-438
JournalUltrasonics Sonochemistry
Volume29
DOIs
Publication statusPublished - 24 Oct 2015

Fingerprint

Ultrasonics
Copper
ultrasonics
Chemical activation
activation
copper
Powders
agglomeration
probes
Colloids
cavitation flow
nanoclusters
noble metals
Baths
Particle Size
Agglomeration
decoupling
Nanoparticles
Oxides
colloids

Bibliographical note

NOTICE: this is the author’s version of a work that was accepted for publication in Ultrasonics Sonochemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Ultrasonics Sonochemistry, [VOL 29, (2015)] DOI: 10.1016/j.ultsonch.2015.10.016

© 2015, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/

Keywords

  • Ultrasound
  • Dispersion
  • Copper nanoparticles
  • Catalytic ink
  • Electroless copper

Cite this

Ultrasound assisted dispersal of a copper nanopowder for electroless copper activation. / Graves, J.; Sugden, M.; Litchfield, R.E.; Hutt, D.A.; Mason, T.J.; Cobley, A.

In: Ultrasonics Sonochemistry, Vol. 29, 24.10.2015, p. 428-438.

Research output: Contribution to journalArticle

Graves, J. ; Sugden, M. ; Litchfield, R.E. ; Hutt, D.A. ; Mason, T.J. ; Cobley, A. / Ultrasound assisted dispersal of a copper nanopowder for electroless copper activation. In: Ultrasonics Sonochemistry. 2015 ; Vol. 29. pp. 428-438.
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