Ultrasonic enhancement of electrochemiluminescence

D.J. Walton; S.S. Phull; D.M. Bates; J.P. Lorimer; T.J. Mason

doi:10.1016/0013-4686(93)85144-N

Ultrasonic enhancement of electrochemiluminescence

D.J. Walton
, S.S. Phull
, D.M. Bates
, J.P. Lorimer
, T.J. Mason

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The electrochemiluminescence of the tris-(2,2′-bipyridine) ruthenium (II) dication in aqueous oxalate and in acetonitrile containing tetrabutylammonium tetrafluoroborate is markedly enhanced by simultaneous irradiation with 40 and 60 kHz ultrasound: edge effects and electrode patchiness are diminished, reproducibility and stability are improved, electrode fouling is minimised, quantum efficiency is increased and lower cell voltages are required.

Original language	English
Pages (from-to)	307-310
Number of pages	4
Journal	Electrochimica Acta
Volume	38
Issue number	2-3
DOIs	https://doi.org/10.1016/0013-4686(93)85144-N
Publication status	Published - Feb 1993

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10.1016/0013-4686(93)85144-N

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title = "Ultrasonic enhancement of electrochemiluminescence",

abstract = "The electrochemiluminescence of the tris-(2,2′-bipyridine) ruthenium (II) dication in aqueous oxalate and in acetonitrile containing tetrabutylammonium tetrafluoroborate is markedly enhanced by simultaneous irradiation with 40 and 60 kHz ultrasound: edge effects and electrode patchiness are diminished, reproducibility and stability are improved, electrode fouling is minimised, quantum efficiency is increased and lower cell voltages are required.",

author = "D.J. Walton and S.S. Phull and D.M. Bates and J.P. Lorimer and T.J. Mason",

year = "1993",

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journal = "Electrochimica Acta",

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TY - JOUR

T1 - Ultrasonic enhancement of electrochemiluminescence

AU - Walton, D.J.

AU - Phull, S.S.

AU - Bates, D.M.

AU - Lorimer, J.P.

AU - Mason, T.J.

PY - 1993/2

Y1 - 1993/2

N2 - The electrochemiluminescence of the tris-(2,2′-bipyridine) ruthenium (II) dication in aqueous oxalate and in acetonitrile containing tetrabutylammonium tetrafluoroborate is markedly enhanced by simultaneous irradiation with 40 and 60 kHz ultrasound: edge effects and electrode patchiness are diminished, reproducibility and stability are improved, electrode fouling is minimised, quantum efficiency is increased and lower cell voltages are required.

AB - The electrochemiluminescence of the tris-(2,2′-bipyridine) ruthenium (II) dication in aqueous oxalate and in acetonitrile containing tetrabutylammonium tetrafluoroborate is markedly enhanced by simultaneous irradiation with 40 and 60 kHz ultrasound: edge effects and electrode patchiness are diminished, reproducibility and stability are improved, electrode fouling is minimised, quantum efficiency is increased and lower cell voltages are required.

UR - https://www.scopus.com/pages/publications/0003910097

U2 - 10.1016/0013-4686(93)85144-N

DO - 10.1016/0013-4686(93)85144-N

M3 - Article

SN - 0013-4686

VL - 38

SP - 307

EP - 310

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 2-3

ER -

Ultrasonic enhancement of electrochemiluminescence

Abstract

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