The oxidation of secondary alcohols with Cr (VI): A kinetic investigation of steric strain

Timothy J. Mason

doi:10.1021/ed059p980

The oxidation of secondary alcohols with Cr (VI): A kinetic investigation of steric strain

Timothy J. Mason

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A titrimetric method for the determination of the rate of acid dichromate oxidation of a series of secondary alcohols; using and excess of the alcohol substrate, pseudo first-order rate constants can be calculated from which estimates of the relative steric strain within these molecules may be obtained.

Original language	English
Pages (from-to)	980-981
Number of pages	2
Journal	Journal of Chemical Education
Volume	59
Issue number	11
DOIs	https://doi.org/10.1021/ed059p980
Publication status	Published - 1 Nov 1982

ASJC Scopus subject areas

General Chemistry
Education

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10.1021/ed059p980

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title = "The oxidation of secondary alcohols with Cr (VI): A kinetic investigation of steric strain",

abstract = "A titrimetric method for the determination of the rate of acid dichromate oxidation of a series of secondary alcohols; using and excess of the alcohol substrate, pseudo first-order rate constants can be calculated from which estimates of the relative steric strain within these molecules may be obtained.",

author = "Mason, \{Timothy J.\}",

year = "1982",

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T1 - The oxidation of secondary alcohols with Cr (VI)

T2 - A kinetic investigation of steric strain

AU - Mason, Timothy J.

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N2 - A titrimetric method for the determination of the rate of acid dichromate oxidation of a series of secondary alcohols; using and excess of the alcohol substrate, pseudo first-order rate constants can be calculated from which estimates of the relative steric strain within these molecules may be obtained.

AB - A titrimetric method for the determination of the rate of acid dichromate oxidation of a series of secondary alcohols; using and excess of the alcohol substrate, pseudo first-order rate constants can be calculated from which estimates of the relative steric strain within these molecules may be obtained.

UR - https://pubs.acs.org/doi/pdf/10.1021/ed059p980

UR - https://www.scopus.com/pages/publications/33845553628

U2 - 10.1021/ed059p980

DO - 10.1021/ed059p980

M3 - Article

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SN - 0021-9584

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JO - Journal of Chemical Education

JF - Journal of Chemical Education

IS - 11

ER -

The oxidation of secondary alcohols with Cr (VI): A kinetic investigation of steric strain

Abstract

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