TY - JOUR
T1 - Sonoelectrochemistry - Cyclohexanoate electrooxidation at 38 kHz and 850 kHz insonation frequencies compared
AU - Walton, D. J.
AU - Phull, S. S.
AU - Geissler, U.
AU - Chyla, A.
AU - Durham, A.
AU - Ryley, S.
AU - Mason, T. J.
AU - Lorimer, J. P.
PY - 2000/6/1
Y1 - 2000/6/1
N2 - Insonation of cyclohexanoate electrooxidation at platinum in methanol produces a similar switch in product distribution from one-electron per-molecule dimers towards products from the two-electron route via the carbocation, irrespective of whether the ultrasonic bath employs 38 or 850 kHz frequencies. However, 850 kHz produces a cleaner reaction and higher yields, with more than two-fold greater yield of total extracted products over the silent system, and one-and-a-half times yield enhancement over insonation at 38 kHz. (C) 2000 Elsevier Science S.A.
AB - Insonation of cyclohexanoate electrooxidation at platinum in methanol produces a similar switch in product distribution from one-electron per-molecule dimers towards products from the two-electron route via the carbocation, irrespective of whether the ultrasonic bath employs 38 or 850 kHz frequencies. However, 850 kHz produces a cleaner reaction and higher yields, with more than two-fold greater yield of total extracted products over the silent system, and one-and-a-half times yield enhancement over insonation at 38 kHz. (C) 2000 Elsevier Science S.A.
KW - Carboxylate electrooxidation
KW - Frequency dependence
KW - Sonoelectrochemistry
KW - Ultrasound
UR - https://www.scopus.com/pages/publications/0033833601
U2 - 10.1016/S1388-2481(00)00054-0
DO - 10.1016/S1388-2481(00)00054-0
M3 - Article
AN - SCOPUS:0033833601
SN - 1388-2481
VL - 2
SP - 431
EP - 435
JO - Electrochemistry Communications
JF - Electrochemistry Communications
IS - 6
ER -