Abstract
Flow through a granular, natural porous media can erode it chemically by dissolving and thus shrinking the solid particles, or mechanically, by removing them. The two-way interplay between the transport of fluids and dissolved solutes and alteration of the porous structure and hence the medium's transport properties is of interest to processes ranging from subsurface energy storage to contamination in groundwater. Here, we conduct a quantitative pore-scale analysis through a combination of numerical simulations and microfluidic experiments. We find that erosion enhances solute dispersion at low Pe (diffusion-dominated) and diminishes it at high Pe. Residence time distribution reveals that mechanical erosion tends to induce non-Fickian transport more than chemical erosion, which we attribute to the differences in their effects on pore size distribution.
Original language | English |
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Article number | e2024GL114312 |
Pages (from-to) | 104773 |
Number of pages | 1 |
Journal | Geophysical Research Letters |
Volume | 52 |
Issue number | 4 |
DOIs | |
Publication status | Published - 28 Feb 2025 |
Bibliographical note
© 2025. The Author(s). This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.Funding
The authors acknowledge resources and support from the Scientific Computing Research Technology Platform (SCRTP) at the University of Warwick, and the HPC facility at the Faculty of Engineering, Environment, and Computing, Coventry University. RH acknowledges support from the Engineering and Physical Sciences Research Council (EP/V050613/1). SA acknowledges funding support from the Natural Environment Research Council (NE/S007350/1).
Funders | Funder number |
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Coventry University | |
University of Warwick | |
Engineering and Physical Sciences Research Council | EP/V050613/1 |
Engineering and Physical Sciences Research Council | |
Natural Environment Research Council | NE/S007350/1 |
Natural Environment Research Council |
Keywords
- direct simulation
- dispersion
- effective diffusivity
- erosion
- porous media
- transport