Nanostructured electrocatalysts immobilised on electrode surfaces and organic film templates

Fakhradin Mirkhalaf, John E. Graves

Research output: Contribution to journalReview articlepeer-review

31 Citations (Scopus)


The development of new electrocatalysts with the aim of enhancing the rate of electrochemical reactions has been a long-term goal of electrochemists. In part, this is due to the great importance of electrocatalysts in energy generation and environmental concerns. In this review, various methods of the preparation of nanostructured electrocatalysts and their applications after attachment to the electrode surface are described. Diazonium chemistry has been extensively used for the preparation and attachment of nanostructured electrocatalysts and this review thus describes the recent developments and applications of this chemistry in electrocatalysis. The preparation of nanostructured electrocatalysts including grafted molecular films and metal nanoparticles physically adsorbed on electrode surfaces and those attached to the surface by molecular links using diazonium chemistry is reviewed. Two methods for the attachment of nanoparticles by simple physical adsorption and by electrochemical deposition on molecular films are described and the electrochemical response of nanostructured electrocatalysts for some of the most common electrochemical reactions is discussed.

Original languageEnglish
Pages (from-to)472-483
Number of pages12
JournalChemical Papers
Issue number5
Publication statusPublished - May 2012


  • Diazonium
  • Electrocatalysts
  • Monolayer protected nanoparticles
  • Nanoparticles
  • Nanostructured materials
  • Size-controlled metal deposition
  • Templated metal nanoparticles

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Biochemistry
  • Industrial and Manufacturing Engineering
  • Materials Chemistry


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