Metal recovery by electrodeposition from a molten salt two-phase cell system

Tazdin Amietszajew, Seetharaman Sridhar, Rohit Bhagat

Research output: Contribution to journalArticle

2 Citations (Scopus)
7 Downloads (Pure)

Abstract

A novel electrochemical recovery method of Co, Cu, Mn and Ni from a reactor based on two immiscible molten phases, to enable selective metal plating, sufficient feedstock dissolution and protection from re-oxidation, was designed and characterized through voltammetry and chronoamperometry. The immiscible phases in the electrolytic cell were NaCl and Na2O-2B2O3 at 1173 K, and the metal feedstock to be recovered was either metal chlorides or metal oxides of Co, Cu, Mn and Ni. Metals could be successfully recovered as plated metal deposits and the formal redox reaction potentials were reported. Metals thermodynamic behavior differences between the cells were analyzed. Analysis of the metal deposits showed that the recovered metals were of high purity (∼99%). This offers an alternative method to recycle valuable metals present in the growing e-waste stream.

Original languageEnglish
Pages (from-to)D515-D521
Number of pages7
JournalJournal of the Electrochemical Society
Volume163
Issue number9
DOIs
Publication statusPublished - 19 Jul 2016
Externally publishedYes

Fingerprint

Metal recovery
Electrodeposition
Molten materials
Salts
Metals
Feedstocks
Deposits
Electrolytic cells
Chronoamperometry
Redox reactions
Voltammetry
Plating
Oxides
Chlorides
Dissolution
Thermodynamics
Recovery
Oxidation

Bibliographical note

Copyright © and Moral Rights are retained by the author(s) and/ or other copyright owners. A copy can be downloaded for personal non-commercial research or study, without prior permission or charge. This item cannot be reproduced or quoted extensively from without first obtaining permission in writing from the copyright holder(s). The content must not be changed in any way or sold commercially in any format or medium without the formal permission of the copyright holders.

Keywords

  • cyclic voltammetry
  • electrochemistry
  • electroplating
  • electroreduction
  • li-ion
  • metal recovery
  • molten salt
  • recycling
  • thermodynamics

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Cite this

Metal recovery by electrodeposition from a molten salt two-phase cell system. / Amietszajew, Tazdin; Sridhar, Seetharaman; Bhagat, Rohit.

In: Journal of the Electrochemical Society, Vol. 163, No. 9, 19.07.2016, p. D515-D521.

Research output: Contribution to journalArticle

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