Interactions between tripodal porphyrin hosts and single walled carbon nanotubes: An experimental and theoretical (DFT) account

Sofia I. Pascu, Navaratnarajah Kuganathan, Lok H. Tong, Robert M.J. Jacobs, Peter J. Barnard, Brian T. Chu, Yoon Huh, Gerard Tobias, Christoph G. Salzmann, Jeremy K.M. Sanders, Malcolm L.H. Green, Jennifer C. Green

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

We describe a strategy for dispersing single walled nanotubes (SWNTs) in organic solvents using supramolecular coating with tailor-made, structurally adjustable tripodal porphyrin receptors. These have the ability to recognise SWNTs from DMF-toluene mixtures. HR TEM, TM AFM and SEM measurements showed that the hosts wrap around individual arc-made SWNTs, giving monodispersed composites in DMF which are stable for weeks. The dispersed composites were studied by Raman and fluorescence spectroscopies, including laser scanning confocal microscopy (for aggregates incorporated in cells). These porphyrin hosts encapsulate SWNTs based on π-π type interactions in an analogous manner to those observed by single crystal X-ray diffraction in their C 60 complexes. These interactions may be further reinforced by porphyrin-porphyrin stacking. Density functional theory (DFT) calculations predicted the structure of the SWNT: porphyrin host complex or composite formed and the binding energies of tripodal porphyrin hosts in composites with either C60 or SWNT as guests.

Original languageEnglish
Pages (from-to)2781-2788
Number of pages8
JournalJournal of Materials Chemistry
Volume18
Issue number24
DOIs
Publication statusPublished - 17 Jun 2008
Externally publishedYes

Fingerprint

Porphyrins
Single-walled carbon nanotubes (SWCN)
Nanotubes
Density functional theory
Composite materials
Confocal microscopy
Fluorescence spectroscopy
Toluene
Binding energy
Organic solvents
Raman spectroscopy
Single crystals
Transmission electron microscopy
Scanning
X ray diffraction
Coatings
Scanning electron microscopy
Lasers

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

Cite this

Interactions between tripodal porphyrin hosts and single walled carbon nanotubes : An experimental and theoretical (DFT) account. / Pascu, Sofia I.; Kuganathan, Navaratnarajah; Tong, Lok H.; Jacobs, Robert M.J.; Barnard, Peter J.; Chu, Brian T.; Huh, Yoon; Tobias, Gerard; Salzmann, Christoph G.; Sanders, Jeremy K.M.; Green, Malcolm L.H.; Green, Jennifer C.

In: Journal of Materials Chemistry, Vol. 18, No. 24, 17.06.2008, p. 2781-2788.

Research output: Contribution to journalArticle

Pascu, SI, Kuganathan, N, Tong, LH, Jacobs, RMJ, Barnard, PJ, Chu, BT, Huh, Y, Tobias, G, Salzmann, CG, Sanders, JKM, Green, MLH & Green, JC 2008, 'Interactions between tripodal porphyrin hosts and single walled carbon nanotubes: An experimental and theoretical (DFT) account' Journal of Materials Chemistry, vol. 18, no. 24, pp. 2781-2788. https://doi.org/10.1039/b719494c
Pascu, Sofia I. ; Kuganathan, Navaratnarajah ; Tong, Lok H. ; Jacobs, Robert M.J. ; Barnard, Peter J. ; Chu, Brian T. ; Huh, Yoon ; Tobias, Gerard ; Salzmann, Christoph G. ; Sanders, Jeremy K.M. ; Green, Malcolm L.H. ; Green, Jennifer C. / Interactions between tripodal porphyrin hosts and single walled carbon nanotubes : An experimental and theoretical (DFT) account. In: Journal of Materials Chemistry. 2008 ; Vol. 18, No. 24. pp. 2781-2788.
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