In metastable β-Ti alloys, nanoscale isothermal ω-phase (ω iso) precipitates are regarded as the nucleation sites for the α strengthening phase. Here we investigate the precipitation kinetics of the ω iso precipitates as a function of cooling rate (air cooling and water quenching) after β-solutionising. A combined in situ small-angle neutron scattering (SANS) and electrical resistivity measurement approach was used during ageing of Ti–5Al–5Mo–5V–3Cr wt% (Ti-5553) alloy at 300 °C and 325 °C up to 8 h. The SANS modelling was consistent with ellipsoid shaped particles for the ω iso precipitates, for both air-cooled and water-quenched samples. The precipitates attained a maximum size (equatorial diameter) of ∼21 nm and ∼17 nm after 2 h and 4 h of ageing the water-quenched and air-cooled samples respectively. Although the air-cooled samples showed delayed nucleation in comparison to water-quenched sample, the volume fraction became approximately the same (∼11%) after ageing for 8 h. The average value of the activation energy for ω iso nucleation from the β-phase matrix was determined as 122 kJ mol −1 from electrical resistivity data using a modified Johnson-Mehl-Avrami-Kolmogorov (JMAK) model. The hardness increased with ageing time, with water quenching leading to a higher final value of hardness than air cooling.
|Journal||Journal of Alloys and Compounds|
|Early online date||6 Nov 2020|
|Publication status||Published - 5 Apr 2021|
Bibliographical noteNOTICE: this is the author’s version of a work that was accepted for publication in Journal of Alloys and Compounds. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Alloys and Compounds, 859, (2021) DOI: 10.1016/j.jallcom.2020.157822
© 2021, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
FunderLloyd’s Register Foundation ( LRF ), UK’s Engineering and Physical Sciences Research Council , EPSRC Early Career Fellowship Scheme, EP/R043973/1.
- Electrical resistivity measurements
- Small-angle neutron scattering
- Titanium alloys
ASJC Scopus subject areas
- Mechanics of Materials
- Mechanical Engineering
- Metals and Alloys
- Materials Chemistry