Hydrogen evolution rate during the corrosion stainless steel in supercritical water

Kashif  Choudhry; Ruth Carvajal Ortiz; Dimitrios  Kallikragas; Igor Svishchev

doi:10.1016/j.corsci.2014.02.019

Hydrogen evolution rate during the corrosion stainless steel in supercritical water

Kashif Choudhry
, Ruth Carvajal Ortiz
, Dimitrios Kallikragas
, Igor Svishchev

Trent University

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

The interaction of water with metal surfaces at high temperatures leads to the significant release of hydrogen gas. A systematic investigation of hydrogen evolution from fresh and oxidized stainless steel (SS316) surfaces is carried out in a tubular reactor, at supercritical water conditions. A linear relationship is found between the reactor surface area and the rate of hydrogen gas released. Results show that the evolution of hydrogen gas is a zero-order reaction, with the activation energy of 105.9 kJ mol−1 for the oxidized surface.

Original language	English
Pages (from-to)	226-233
Number of pages	8
Journal	Corrosion Science
Volume	83
Early online date	18 Feb 2014
DOIs	https://doi.org/10.1016/j.corsci.2014.02.019
Publication status	Published - Jun 2014
Externally published	Yes

Access to Document

10.1016/j.corsci.2014.02.019

Cite this

@article{2bd79ee17a6d4fadb83ee1f0cd85a2e7,

title = "Hydrogen evolution rate during the corrosion stainless steel in supercritical water",

abstract = "The interaction of water with metal surfaces at high temperatures leads to the significant release of hydrogen gas. A systematic investigation of hydrogen evolution from fresh and oxidized stainless steel (SS316) surfaces is carried out in a tubular reactor, at supercritical water conditions. A linear relationship is found between the reactor surface area and the rate of hydrogen gas released. Results show that the evolution of hydrogen gas is a zero-order reaction, with the activation energy of 105.9 kJ mol−1 for the oxidized surface.",

author = "Kashif Choudhry and \{Carvajal Ortiz\}, Ruth and Dimitrios Kallikragas and Igor Svishchev",

year = "2014",

month = jun,

doi = "10.1016/j.corsci.2014.02.019",

language = "English",

volume = "83",

pages = "226--233",

journal = "Corrosion Science",

issn = "0010-938X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Hydrogen evolution rate during the corrosion stainless steel in supercritical water

AU - Choudhry, Kashif

AU - Carvajal Ortiz, Ruth

AU - Kallikragas, Dimitrios

AU - Svishchev, Igor

PY - 2014/6

Y1 - 2014/6

N2 - The interaction of water with metal surfaces at high temperatures leads to the significant release of hydrogen gas. A systematic investigation of hydrogen evolution from fresh and oxidized stainless steel (SS316) surfaces is carried out in a tubular reactor, at supercritical water conditions. A linear relationship is found between the reactor surface area and the rate of hydrogen gas released. Results show that the evolution of hydrogen gas is a zero-order reaction, with the activation energy of 105.9 kJ mol−1 for the oxidized surface.

AB - The interaction of water with metal surfaces at high temperatures leads to the significant release of hydrogen gas. A systematic investigation of hydrogen evolution from fresh and oxidized stainless steel (SS316) surfaces is carried out in a tubular reactor, at supercritical water conditions. A linear relationship is found between the reactor surface area and the rate of hydrogen gas released. Results show that the evolution of hydrogen gas is a zero-order reaction, with the activation energy of 105.9 kJ mol−1 for the oxidized surface.

U2 - 10.1016/j.corsci.2014.02.019

DO - 10.1016/j.corsci.2014.02.019

M3 - Article

SN - 0010-938X

VL - 83

SP - 226

EP - 233

JO - Corrosion Science

JF - Corrosion Science

ER -

Hydrogen evolution rate during the corrosion stainless steel in supercritical water

Abstract

Access to Document

Fingerprint

Cite this