Aerosols produced over forests impair visibility and may affect climate by scattering and absorbing solar radiation and by serving as cloud condensation nuclei. Here, we introduce, to our knowledge, a new route to secondary organic aerosol formation from isoprene and its gas-phase oxidation products, methacrolein and methacrylic acid, namely, multiphase acid-catalysed oxidation with hydrogen peroxide, a perfect analogue to atmospheric sulphate formation. We demonstrate that the formation of major secondary organic aerosol components that are present in natural forest aerosols collected at K-puszta, Hungary, during the summer of 2003, namely, 2-methyltetrols and 2,3-dihydroxymethacrylic acid, can be explained by this mechanism.
- Secondary organic aerosol
- Biogenic hydrocarbons
Claeys, M., Wang, W., Ion, A. C., Kourtchev, I., Gelencsér, A., & Maenhaut, W. (2004). Formation of secondary organic aerosols from isoprene and its gas-phase oxidation products through reaction with hydrogen peroxide. Atmospheric Environment, 38(25), 4093-4098. https://doi.org/10.1016/j.atmosenv.2004.06.001