Fabrication of anodized Li[Ni 1/3 Co 1/3 Mn 1/3 ]O 2 as cathode to enhanced the capacities for energy storage and conversion device

R. M. Gnanamuthu, M. Sasidharan, Kumaran Vediappan, S. Mohan, Chang Woo Lee, Rohit Bhagat

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

We report electrochemical properties of Li[Ni 1/3 Co 1/3 Mn 1/3 ]O 2 (NCM) active material coated onto anodized aluminium foil are systematically studied, for the first time, to Li-ion rechargeable battery application. The purpose of the anodized layer which is highly porous to compare with that pristine conventional Al substrate. Anodization was effected over aluminium current collector using orthophosphoric acid to increase porosity and create a hard electrically insulating with NCM material. The coated of the NCM active materials on both before and after anodization with aluminium substrates as a current collector were characterized by state of art techniques. The anodized NCM cathode materials exhibited an initial discharge capacity of 171 mAh g −1 as against the conventional NCM of 161 mAh g −1 , which corresponds to a 6.2% improvement in capacity. The columbic efficiency is approximately 99.5% at 0.1 C rate in cut-off potential range 4.2–2.5 V.

Original languageEnglish
Pages (from-to)932-937
Number of pages6
JournalJournal of Alloys and Compounds
Volume708
Early online date11 Jan 2017
DOIs
Publication statusPublished - Jun 2017
Externally publishedYes

Fingerprint

Energy conversion
Energy storage
Cathodes
Aluminum
Fabrication
Orthophosphoric acid
Coated materials
Aluminum foil
Secondary batteries
Substrates
Electrochemical properties
Porosity
Ions

Keywords

  • Adhesion
  • Cathode materials
  • Electrochemical anodizing
  • Energy storage
  • Li-ion batteries

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Fabrication of anodized Li[Ni 1/3 Co 1/3 Mn 1/3 ]O 2 as cathode to enhanced the capacities for energy storage and conversion device. / Gnanamuthu, R. M.; Sasidharan, M.; Vediappan, Kumaran; Mohan, S.; Lee, Chang Woo; Bhagat, Rohit.

In: Journal of Alloys and Compounds, Vol. 708, 06.2017, p. 932-937.

Research output: Contribution to journalArticle

Gnanamuthu, R. M. ; Sasidharan, M. ; Vediappan, Kumaran ; Mohan, S. ; Lee, Chang Woo ; Bhagat, Rohit. / Fabrication of anodized Li[Ni 1/3 Co 1/3 Mn 1/3 ]O 2 as cathode to enhanced the capacities for energy storage and conversion device. In: Journal of Alloys and Compounds. 2017 ; Vol. 708. pp. 932-937.
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abstract = "We report electrochemical properties of Li[Ni 1/3 Co 1/3 Mn 1/3 ]O 2 (NCM) active material coated onto anodized aluminium foil are systematically studied, for the first time, to Li-ion rechargeable battery application. The purpose of the anodized layer which is highly porous to compare with that pristine conventional Al substrate. Anodization was effected over aluminium current collector using orthophosphoric acid to increase porosity and create a hard electrically insulating with NCM material. The coated of the NCM active materials on both before and after anodization with aluminium substrates as a current collector were characterized by state of art techniques. The anodized NCM cathode materials exhibited an initial discharge capacity of 171 mAh g −1 as against the conventional NCM of 161 mAh g −1 , which corresponds to a 6.2{\%} improvement in capacity. The columbic efficiency is approximately 99.5{\%} at 0.1 C rate in cut-off potential range 4.2–2.5 V.",
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AU - Lee, Chang Woo

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