Experimental and Numerical Study of Low Temperature Methane Steam Reforming for Hydrogen Production

Martin Khzouz, Evangelos Gkanas

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12 Citations (Scopus)
71 Downloads (Pure)

Abstract

Low temperature methane steam reforming for hydrogen production, using experimental developed Ni/Al2O3 catalysts is studied both experimentally and numerically. The catalytic activity measurements were performed at a temperature range of 500–700 °C with steam to carbon ratio (S/C) of 2 and 3 under atmospheric pressure conditions. A mathematical analysis to evaluate the reaction feasibility at all different conditions that have been applied by using chemical equilibrium with applications (CEA) software and in addition, a mathematical model focused on the kinetics and the thermodynamics of the reforming reaction is introduced and applied using a commercial finite element analysis software (COMSOL Multiphysics 5.0). The experimental results were employed to validate the extracted simulation data based on the yields of the produced H2, CO2 and CO at different temperatures. A maximum hydrogen yield of 2.7 mol/mol-CH4 is achieved at 700 °C and S/C of 2 and 3. The stability of the 10%Ni/Al2O3 catalyst shows that the catalyst is prone to deactivation as supported by Thermogravimetric Analysis TGA results
Original languageEnglish
Article number5
JournalCatalysts
Volume8
Issue number1
DOIs
Publication statusPublished - 25 Dec 2017

Bibliographical note

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

Keywords

  • hydrogen production
  • methane steam reformer
  • reforming catalysts
  • reforming modelling
  • Ni based catalyst

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