Enhancement of an Ullmann coupling reaction induced by ultrasound

J. Lindley; J. P. Lorimer; T. J. Mason

doi:10.1016/0041-624X(86)90108-3

Enhancement of an Ullmann coupling reaction induced by ultrasound

J. Lindley, J. P. Lorimer, T. J. Mason

Research output: Contribution to journal › Article › peer-review

52 Citations (Scopus)

Abstract

Ultrasonic irradiation during the Ullmann coupling reaction of 2-iodonitrobenzene in the presence of a 4-fold excess of copper powder leads to a 50-fold increase in reactivity. Although sonication has been shown to reduce the particle size of the copper this factor alone is not sufficient to explain the large rate enhancement observed. Ultrasonic irradiation may well be serving to sweep reacted species away from the metal surface exposing a fresh surface on which reaction can take place.

Original language	English
Pages (from-to)	292-293
Number of pages	2
Journal	Ultrasonics
Volume	24
Issue number	5
DOIs	https://doi.org/10.1016/0041-624X(86)90108-3
Publication status	Published - Sept 1986

Keywords

chemical reactions
sonochemistry
Ullmann coupling reaction

ASJC Scopus subject areas

Acoustics and Ultrasonics

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10.1016/0041-624X(86)90108-3

Cite this

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title = "Enhancement of an Ullmann coupling reaction induced by ultrasound",

abstract = "Ultrasonic irradiation during the Ullmann coupling reaction of 2-iodonitrobenzene in the presence of a 4-fold excess of copper powder leads to a 50-fold increase in reactivity. Although sonication has been shown to reduce the particle size of the copper this factor alone is not sufficient to explain the large rate enhancement observed. Ultrasonic irradiation may well be serving to sweep reacted species away from the metal surface exposing a fresh surface on which reaction can take place.",

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author = "J. Lindley and Lorimer, \{J. P.\} and Mason, \{T. J.\}",

year = "1986",

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T1 - Enhancement of an Ullmann coupling reaction induced by ultrasound

AU - Lindley, J.

AU - Lorimer, J. P.

AU - Mason, T. J.

PY - 1986/9

Y1 - 1986/9

N2 - Ultrasonic irradiation during the Ullmann coupling reaction of 2-iodonitrobenzene in the presence of a 4-fold excess of copper powder leads to a 50-fold increase in reactivity. Although sonication has been shown to reduce the particle size of the copper this factor alone is not sufficient to explain the large rate enhancement observed. Ultrasonic irradiation may well be serving to sweep reacted species away from the metal surface exposing a fresh surface on which reaction can take place.

AB - Ultrasonic irradiation during the Ullmann coupling reaction of 2-iodonitrobenzene in the presence of a 4-fold excess of copper powder leads to a 50-fold increase in reactivity. Although sonication has been shown to reduce the particle size of the copper this factor alone is not sufficient to explain the large rate enhancement observed. Ultrasonic irradiation may well be serving to sweep reacted species away from the metal surface exposing a fresh surface on which reaction can take place.

KW - chemical reactions

KW - sonochemistry

KW - Ullmann coupling reaction

UR - https://www.scopus.com/pages/publications/0000297349

U2 - 10.1016/0041-624X(86)90108-3

DO - 10.1016/0041-624X(86)90108-3

M3 - Article

AN - SCOPUS:0000297349

SN - 0041-624X

VL - 24

SP - 292

EP - 293

JO - Ultrasonics

JF - Ultrasonics

IS - 5

ER -

Enhancement of an Ullmann coupling reaction induced by ultrasound

Abstract

Keywords

ASJC Scopus subject areas

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