Effect of ultrasound on the solvolysis of 2-chloro-2-methylpropane in aqueous alcoholic solvents

J. P. Lorimer; T. J. Mason; B. P. Mistry

doi:10.1016/0041-624X(87)90006-0

Effect of ultrasound on the solvolysis of 2-chloro-2-methylpropane in aqueous alcoholic solvents

J. P. Lorimer
, T. J. Mason
, B. P. Mistry

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Ultrasonic irradiation was found to acclerate the solvolysis of 2-chloro-2-methylpropane in aqueous ethanol mixtures. The effects were more marked at lower temperatures and higher alcohol compositions, with a 20-fold rate acceleration occurring at 10°C and 60 wt%. The kinetic data were analysed with reference to the variation in solvent structure and vapour pressure. Enthalpies and heat capacities of activation in both the presence and absence of ultrasound were also determined. The result spresented in this Paper confirm the existence of a region of maximum structure in the binary mixture.

Original language	English
Pages (from-to)	23-28
Number of pages	6
Journal	Ultrasonics
Volume	25
Issue number	1
DOIs	https://doi.org/10.1016/0041-624X(87)90006-0
Publication status	Published - Jan 1987

Keywords

solvolysis
sonochemistry

ASJC Scopus subject areas

Acoustics and Ultrasonics

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10.1016/0041-624X(87)90006-0

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title = "Effect of ultrasound on the solvolysis of 2-chloro-2-methylpropane in aqueous alcoholic solvents",

abstract = "Ultrasonic irradiation was found to acclerate the solvolysis of 2-chloro-2-methylpropane in aqueous ethanol mixtures. The effects were more marked at lower temperatures and higher alcohol compositions, with a 20-fold rate acceleration occurring at 10°C and 60 wt\%. The kinetic data were analysed with reference to the variation in solvent structure and vapour pressure. Enthalpies and heat capacities of activation in both the presence and absence of ultrasound were also determined. The result spresented in this Paper confirm the existence of a region of maximum structure in the binary mixture.",

keywords = "solvolysis, sonochemistry",

author = "Lorimer, \{J. P.\} and Mason, \{T. J.\} and Mistry, \{B. P.\}",

year = "1987",

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AU - Lorimer, J. P.

AU - Mason, T. J.

AU - Mistry, B. P.

PY - 1987/1

Y1 - 1987/1

N2 - Ultrasonic irradiation was found to acclerate the solvolysis of 2-chloro-2-methylpropane in aqueous ethanol mixtures. The effects were more marked at lower temperatures and higher alcohol compositions, with a 20-fold rate acceleration occurring at 10°C and 60 wt%. The kinetic data were analysed with reference to the variation in solvent structure and vapour pressure. Enthalpies and heat capacities of activation in both the presence and absence of ultrasound were also determined. The result spresented in this Paper confirm the existence of a region of maximum structure in the binary mixture.

AB - Ultrasonic irradiation was found to acclerate the solvolysis of 2-chloro-2-methylpropane in aqueous ethanol mixtures. The effects were more marked at lower temperatures and higher alcohol compositions, with a 20-fold rate acceleration occurring at 10°C and 60 wt%. The kinetic data were analysed with reference to the variation in solvent structure and vapour pressure. Enthalpies and heat capacities of activation in both the presence and absence of ultrasound were also determined. The result spresented in this Paper confirm the existence of a region of maximum structure in the binary mixture.

KW - solvolysis

KW - sonochemistry

UR - https://www.scopus.com/pages/publications/0022502371

U2 - 10.1016/0041-624X(87)90006-0

DO - 10.1016/0041-624X(87)90006-0

M3 - Article

AN - SCOPUS:0022502371

SN - 0041-624X

VL - 25

SP - 23

EP - 28

JO - Ultrasonics

JF - Ultrasonics

IS - 1

ER -

Effect of ultrasound on the solvolysis of 2-chloro-2-methylpropane in aqueous alcoholic solvents

Abstract

Keywords

ASJC Scopus subject areas

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