Beneficial Effect of Manganese(II) Ions on the Morphology of Polyol Synthesised Silver Nanowires

C. Prabukumar, K. Udaya Bhat

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Silver nanowires (Ag NWs) is a potential material to be used as the transparent conductive electrode (TCE) material, in the flexible electronic applications. The polyol method is the commonly used technique to synthesis the silver nanowires. The growth of the silver nanowires is facilitated by the oxidative etching of the silver seed particles. The present work investigates the influence of the manganese(II) ions to promote the growth of silver nanowires. The manganese(II) ions, due to its multiple oxidation states, play an essential role in removing the dissolved atomic oxygen, which prevent the growth of longer nanowires. Its effect on the length and diameter of the silver nanowires is studied in detail with different concentration levels. Characterization tools, such as X-ray diffractometry, electron microscopy (FESEM and TEM) and UV–VIS spectroscopy are used to characterise the synthesised silver nanowires. The addition of manganese(II) ions alters the aspect ratio of the silver nanowires that in turn, affects the optoelectrical properties of the TCE films. By using the synthesised silver nanowires, transparent heaters are successfully fabricated and their performances under different conditions are evaluated. Graphic Abstract: [Figure not available: see fulltext.].

Original languageEnglish
Pages (from-to)264-275
Number of pages12
JournalElectronic Materials Letters
Volume16
Issue number3
Early online date2 Apr 2020
DOIs
Publication statusPublished - 1 May 2020
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2020, The Korean Institute of Metals and Materials.

Funder

Prabukumar would like to thank NIT Karnataka for providing financial support in the form of Institute fellowship. The author is thankful to Dr. Saumen Mandal, Assistant Professor, Department of Metallurgical and Materials Engineering, NITK for providing four-probe measurement setup and Prof. M. N. Satyanarayan, Department of Physics, NITK for providing UV–VIS spectroscopy and Keithley 2400 source meter. The author wants to thank Mr. Prashant Huilgol and Mr. M. S. Nandana, Department of Metallurgical and Materials Engineering, NITK for their help in TEM images.

Prabukumar would like to thank NIT Karnataka for providing financial support in the form of Institute fellowship. The author is thankful to Dr. Saumen Mandal, Assistant Professor, Department of Metallurgical and Materials Engineering, NITK for providing four-probe measurement setup and Prof. M. N. Satyanarayan, Department of Physics, NITK for providing UV?VIS spectroscopy and Keithley 2400 source meter. The author wants to thank Mr. Prashant Huilgol and Mr. M. S. Nandana, Department of Metallurgical and Materials Engineering, NITK for their help in TEM images.

Keywords

  • Electronic materials
  • Oxygen scavenger
  • Silver nanowires
  • Transparent heaters

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

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