Active site isolation in bismuth-poisoned Pd/SiO2 catalysts for selective hydrogenation of furfural

Nikolai Cherkasov, Antonio Jose Exposito, Moom Aw, Javier Fernandez Garcia, Steven Huband, Jeremy Sloan, Larysa Paniwnyk, Evgeny Rebrov

    Research output: Contribution to journalArticlepeer-review

    31 Citations (Scopus)

    Abstract

    Active site isolation in furfural (FA) hydrogenation was studied by poisoning a Pd catalyst with bismuth. A solution of FA in water was hydrogenated over a 5 wt% Pd/SiO 2 catalyst in a batch reactor at various reaction temperatures and pressures. Furfuryl alcohol (FAL) was an intermediate product which was further hydrogenated into tetrahydrofurfuryl alcohol (TFAL) or cyclopentanone (CPA) and cyclopentanol (CPOL). While application of hydrogen pressure above 30 bar had little effect on the hydrogenation kinetics, a reaction temperature affected product distribution and the main product changed from TFAL (at 50 °C) to FAL (100 and 150 °C). Poisoning the catalyst with Bi decreased the number of available active sites but had little effect on the turn-over frequencies, most likely because of the absence of electronic effects of Bi on Pd nanoparticles. The main reaction product over the Bi-poisoned catalyst was FAL with no FA oligomerisation products. At a reaction temperature of 150 °C, CPA was formed with a 57% yield. Considering that Bi preferentially poisons step sites of Pd, the comparison of the product distribution between the Pd and Pd-Bi catalyst as well as the literature data for the alloy Pd-Cu catalysts indicates that the active site isolation observed in the Pd-Bi catalysts is responsible for the increasing FAL and CPA selectivities and elimination of oligomer by-products.

    Original languageEnglish
    Pages (from-to)183-191
    Number of pages9
    JournalApplied Catalysis A: General
    Volume570
    Early online date20 Nov 2018
    DOIs
    Publication statusPublished - 25 Jan 2019

    Keywords

    • Active site
    • Bismuth
    • Hydrogenation
    • Palladium
    • Poison

    ASJC Scopus subject areas

    • Catalysis
    • Process Chemistry and Technology

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