Active site isolation in bismuth-poisoned Pd/SiO2 catalysts for selective hydrogenation of furfural

Nikolai Cherkasov, Antonio Jose Exposito, Moom Aw, Javier Fernandez Garcia, Steven Huband, Jeremy Sloan, Larysa Paniwnyk, Evgeny Rebrov

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Active site isolation in furfural (FA) hydrogenation was studied by poisoning a Pd catalyst with bismuth. A solution of FA in water was hydrogenated over a 5 wt% Pd/SiO 2 catalyst in a batch reactor at various reaction temperatures and pressures. Furfuryl alcohol (FAL) was an intermediate product which was further hydrogenated into tetrahydrofurfuryl alcohol (TFAL) or cyclopentanone (CPA) and cyclopentanol (CPOL). While application of hydrogen pressure above 30 bar had little effect on the hydrogenation kinetics, a reaction temperature affected product distribution and the main product changed from TFAL (at 50 °C) to FAL (100 and 150 °C). Poisoning the catalyst with Bi decreased the number of available active sites but had little effect on the turn-over frequencies, most likely because of the absence of electronic effects of Bi on Pd nanoparticles. The main reaction product over the Bi-poisoned catalyst was FAL with no FA oligomerisation products. At a reaction temperature of 150 °C, CPA was formed with a 57% yield. Considering that Bi preferentially poisons step sites of Pd, the comparison of the product distribution between the Pd and Pd-Bi catalyst as well as the literature data for the alloy Pd-Cu catalysts indicates that the active site isolation observed in the Pd-Bi catalysts is responsible for the increasing FAL and CPA selectivities and elimination of oligomer by-products.

Original languageEnglish
Pages (from-to)183-191
Number of pages9
JournalApplied Catalysis A: General
Volume570
Early online date20 Nov 2018
DOIs
Publication statusPublished - 25 Jan 2019

Keywords

  • Active site
  • Bismuth
  • Hydrogenation
  • Palladium
  • Poison

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Fingerprint Dive into the research topics of 'Active site isolation in bismuth-poisoned Pd/SiO2 catalysts for selective hydrogenation of furfural'. Together they form a unique fingerprint.

  • Cite this

    Cherkasov, N., Exposito, A. J., Aw, M., Fernandez Garcia, J., Huband, S., Sloan, J., ... Rebrov, E. (2019). Active site isolation in bismuth-poisoned Pd/SiO2 catalysts for selective hydrogenation of furfural. Applied Catalysis A: General, 570, 183-191. https://doi.org/10.1016/j.apcata.2018.11.016